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Moist air: saturation vapour pressure, and the density and speed of sound of humid air.
Air is treated as an ideal mixture of dry air (the 1976 standard’s M₀, γ = 1.4) and water
vapour (see docs/physics/atmosphere.md):
x_v = e / p vapour mole fraction (Dalton)
M = (1 − x_v) M₀ + x_v M_v mixture molar mass
ρ = p M / (R* T) = p / (R_d T_v) density
T_v = T / (1 − x_v (1 − M_v/M₀)) virtual temperature (WMO-No. 8 eq. 12.18)
γ = C_p / (C_p − R*), C_p = (1 − x_v) (7/2) R* + x_v 4 R*
a = (γ R* T / M)^½Water vapour’s molar heat capacity is taken as 4 R*, the rigid nonlinear molecule
(33.26 J/(mol·K)); the ideal-gas value near 300 K is about 1% higher, which moves a by 0.009%
at 30 °C and saturation. Viscosity stays dry air’s: by Wilke’s mixing rule, water vapour
lowers it by 2.1% at 30 °C and saturation, which changes turbulent skin friction by about
0.4%.
Saturation vapour pressure over liquid water follows WMO-No. 8, Guide to Instruments and Methods of Observation, Vol. I (2023), Annex 4.B, eq. 4.B.1, at every temperature: radiosonde relative humidity is always reported relative to water, even below 0 °C.
Constants§
- WATER_
VAPOUR_ MOLECULAR_ WEIGHT_ KG_ PER_ KMOL - Molar mass of water vapour
M_v, kg/kmol (A. Picard et al., “Revised formula for the density of moist air (CIPM-2007)”, Metrologia 45, 149–155 (2008), section 2.1).
Functions§
- moist_
air - The state of moist air at
temperature_kandpressure_pawith water vapour at partial pressurevapour_pressure_pa. The vapour mole fraction is capped at 1. - saturation_
vapour_ pressure_ pa - Saturation vapour pressure of pure water vapour over a plane surface of liquid water, Pa, at
temperature
temperature_k. WMO-No. 8 (2023), Vol. I, Annex 4.B, eq. 4.B.1, withtin °C: - vapour_
pressure_ pa - The vapour pressure, Pa, of air at
temperature_kwith relative humidityrelative_humidity(a fraction, relative to liquid water):e = U e_w(T).